Morphological analysis of ag doped on tio2/ti prepared via anodizing and thermal oxidation methods

Wibowo D., Muzakkar M.Z., Maulidiyah M., Nurdin M., Saad S.K.M., Umar A.A.

Department of Environmental Engineering, Faculty of Engineering, Universitas Muhammadiyah Kendari, Southeast Sulawesi, Kendari, 93117, Indonesia; Department of Chemistry, Faculty of Mathematics and Natural Sciences, Universitas Halu Oleo, Southeast Sulawesi, Kendari, 93231, Indonesia; Institute Microengineering and Nanoelectronics, Pusat Penyelidikan, Universiti Kebangsaan Malaysia UKM, Bangi, Selangor, 43600, Malaysia


Abstract

In this work, we present the morphology analysis of TiO2/Ti prepared via anodizing and thermal oxidation (TO) methods and doped by Ag-TiO2 sol-gel nanocomposites through liquid phase deposition (LPD) technique. The comparative morphology of both semiconductors has been observed to inform the catalysis preparation for better morphology structures to the photocatalytic performance. Based on these results, we report that the TiO2/Ti prepared via anodizing method exhibits TiO2 nanotubes arrays (TNTAs) formed like honeycomb structures, while the TiO2/Ti TO (TTO) has diverse size structures. The neat arrangement of TNTAs has a larger surface area and pore volume than TTO structures, which can expose more adsorption and reaction sites, resulting in higher catalytic activity. Uniquely, both semiconductors, after coated by Ag-TiO2 sol-gel, show lamellar sediments covering the surface of TNTAs and TTO. We believe that the anodizing method is a good ability for photocatalysis compared with TTO in terms of small surface area and nanosize structures. © 2021 by the authors.

Anodizing; Morphology; Silver; Thermal; TiO2


Journal

Biointerface Research in Applied Chemistry

Publisher: AMG Transcend Association

Volume 12, Issue 2, Art No , Page 1421 – 1427, Page Count


Journal Link: https://www.scopus.com/inward/record.uri?eid=2-s2.0-85110101587&doi=10.33263%2fBRIAC122.14211427&partnerID=40&md5=9d4d7bd6426ca4350676633b4ac348f9

doi: 10.33263/BRIAC122.14211427

Issn: 20695837

Type:


References

Kamarulzaman, U.A., Rahman, M.Y.A., Su’ait, M.S., Umar, A.A., NickelPalladium Alloy–Reduced Graphene Oxide as Counter Electrode for Dye-Sensitized Solar Cells (2021) Journal of Molecular Liquids, 326, p. 115289; Jia, J., Sun, W., Zhang, Q., Zhang, X., Hu, X., Liu, E., Fan, J., Inter-Plane Heterojunctions within 2D/2D FeSe2/g-C3N4 Nanosheet Semiconductors for Photocatalytic Hydrogen Generation (2020) Applied Catalysis B: Environmental, 261, p. 118249; Natsir, M., Putri, Y.I., Wibowo, D., Maulidiyah, M., Salim, L.O.A., Azis, T., Bijang, C.M., Arham, Z., Effects of Ni–TiO2 Pillared Clay–Montmorillonite Composites for Photocatalytic Enhancement Against Reactive Orange Under Visible Light (2021) Journal of Inorganic and Organometallic Polymers and Materials, , https://doi.org/10.1007/s10904-021-01980-9; Putri, A.E., Roza, L., Budi, S., Umar, A.A., Fauzia, V., Tuning the Photocatalytic Activity of Nanocomposite ZnO Nanorods by Shape-Controlling the Bimetallic AuAg Nanoparticles (2021) Applied Surface Science, 536, p. 147847; Mursalim, L.O., Ruslan, A.M., Safitri, R.A., Azis, T., Maulidiyah, Wibowo, D., Nurdin, M., Synthesis and Photoelectrocatalytic Performance of Mn-N-TiO2/Ti Electrode for Electrochemical Sensor (2017) IOP Conference Series: Materials Science and Engineering, 267, p. 012006. , https://doi.org/10.1088/1757-899X/267/1/012006; Maulidiyah, M., Wibowo, D., Herlin, H., Andarini, M.L., Ruslan; Nurdin, M. Plasmon Enhanced by Ag-Doped S-TiO2/Ti Electrode as Highly Effective Photoelectrocatalyst for Degradation of Methylene Blue (2017) Asian Journal of Chemistry, 29, pp. 2504-2508. , https://doi.org/10.14233/ajchem.2017.20836; Wibowo, D, Maulidiyah, Ruslan, Azis, A, Nurdin, M., A High-Performance Electrochemical Sensor Based on FeTiO3 Synthesis Coated on Conductive Substrates (2018) Analytical and Bioanalytical Electrochemistry, 10, pp. 465-477; Wibowo, D., Ruslan, Maulidiyah, Nurdin, M., Determination of COD Based on Photoelectrocatalysis of FeTiO3.TiO2/Ti Electrode (2017) IOP Conference Series: Materials Science and Engineering, 267, p. 012007. , https://doi.org/10.1088/1757-899X/267/1/012007; Maulidiyah, M., Azis, T., Lindayani, L., Wibowo, D., Ode, L., Salim, A., Aladin, A., Nurdin, M., Sol-Gel TiO2/Carbon Paste Electrode Nanocomposites for Electrochemical-Assisted Sensing of Fipronil Pesticide (2019) Journal of Electrochemical Science and Technology, 10, pp. 394-401; Wibowo, D., Muzakkar, M.Z., Saad, S.K.M., Mustapa, F., Maulidiyah, M., Nurdin, M., Umar, A.A., Enhanced Visible Light-Driven Photocatalytic Degradation Supported by Au-TiO2 Coral-Needle Nanoparticles (2020) Journal of Photochemistry and Photobiology A: Chemistry, p. 112589; Muzakkar, M.Z., Nurdin, M., Ismail, I., Maulidiyah, M., Wibowo, D., Ratna, R., Saad, S.K.M., Umar, A.A., TiO2 Coated-Asphalt Buton Photocatalyst for High-Performance Motor Vehicles Gas Emission Mitigation (2019) Emission Control Science and Technology, 6, pp. 28-36; Mohar, R.S., Sugihartono, I., Fauzia, V., Umar, A.A., Dependence of Optical Properties of Mg-Doped ZnO Nanorods on Al Dopant (2020) Surfaces and Interfaces, 19, p. 100518; Maulidiyah, M., Natsir, M., Fitrianingsih, F., Arham, Z., Wibowo, D., Nurdin, M., Lignin Degradation of Oil Palm Empty Fruit Bunches Using TiO2 photocatalyst as Antifungal of Fusarium Oxysporum (2017) Oriental Journal of Chemistry, 33, pp. 3101-3106. , https://doi.org/10.13005/ojc/330651; Nurdin, M., Zaeni, A., Rammang, E.T., Maulidiyah, M., Wibowo, D., Reactor Design Development of Chemical Oxygen Demand Flow System and Its Application (2017) Analytical and Bioanalytical Electrochemistry, 9, pp. 480-494; Nurdin, M., Yanti, N.A., Suciani, Watoni, A.H., Maulidiyah, Aladin, A., Wibowo, D., Efficiency of Ilmenite Photocatalyst Material as Modelling for Antimicrobial Activity (2018) Asian Journal of Chemistry, 30, pp. 1590-1592. , https://doi.org/10.14233/ajchem.2018.21270; Dhayal, M., Kapoor, R., Goury, P., Ranjan, R., Kar, S., Kumar, K., Pande, G., Strategies to Prepare TiO2 Thin Films, Doped with Transition Metal Ions, That Exhibit Speci Fi c Physicochemical Properties to Support Osteoblast Cell Adhesion and Proliferation (2014) Materials Science & Engineering C, 37, pp. 99-107. , https://doi.org/10.1016/j.msec.2013.12.035; Nurdin, M., Azis, T., Maulidiyah, M., Aladin, A., Hafid, N.A., Salim, L.O.A., Wibowo, D., Photocurrent Responses of Metanil Yellow and Remazol Red B Organic Dyes by Using TiO2/Ti Electrode (2018) IOP Conference Series: Materials Science and Engineering, 367, p. 012048; Nurdin, M., Agusu, L., Putra, A.A.M., Maulidiyah, M., Arham, Z., Wibowo, D., Muzakkar, M.Z., Umar, A.A., Synthesis and Electrochemical Performance of Graphene-TiO2-Carbon Paste Nanocomposites Electrode in Phenol Detection (2019) Journal of Physics and Chemistry of Solids, 131. , https://doi.org/10.1016/j.jpcs.2019.03.014; Maulidiyah, M., Wijawan, I.B.P., Wibowo, D., Aladin, A., Hamzah, B., Nurdin, M., Photoelectrochemical Performance of TiO2/Ti Electrode for Organic Compounds (2018) IOP Conference Series: Materials Science and Engineering, 367, p. 012060; Nurdin, M., Prabowo, O.A., Arham, Z., Wibowo, D., Maulidiyah, M., Saad, S.K.M., Umar, A.A., Highly Sensitive Fipronil Pesticide Detection on Ilmenite (FeO.TiO2)-Carbon Paste Composite Electrode (2019) Surfaces and Interfaces, 16. , https://doi.org/10.1016/j.surfin.2019.05.008; Muzakkar, M.Z., Umar, A.A., Ilham, I., Saputra, Z., Zulfikar, L., Chalcogenide Material as High Photoelectrochemical Performance Se Doped TiO2/Ti Electrode: Its Application for Rhodamine B Degradation (2019) Journal of Physics: Conference Series, 1242, pp. 1-8; Maulidiyah, Azis, T., Nurwahidah, A.T., Wibowo, D., Nurdin, M., Photoelectrocatalyst of Fe Co-Doped N-TiO2/Ti Nanotubes: Pesticide Degradation of Thiamethoxam under UV–Visible Lights (2017) Environmental Nanotechnology, Monitoring and Management, 8. , https://doi.org/10.1016/j.enmm.2017.06.002; Akple, M.S., Chimmikuttanda, S.P., Takyi, G.K.S., Elloh, V.W., Fabrication and Density Functional Theory Calculations of Bromine Doped Carbon Nitride Nanosheets with Enhanced Photocatalytic Reduction of Co2 into Solar Fuels (2021) Biointerface Research in Applied Chemistry, 11, pp. 14602-14619. , https://doi.org/10.33263/BRIAC116.1460214619; Selima, S.S., (2022) Structural, Magnetic, Optical Properties and Photocatalytic Activity of Nanocrystalline Cobalt Ferrite Prepared by Three Different Methods, 12, pp. 1335-1351; Nurdin, M., Dali, N., Irwan, I., Maulidiyah, M., Arham, Z., Ruslan, R., Hamzah, B., Wibowo, D., Selectivity Determination of Pb 2+ Ion Based on TiO2-Ionophores BEK6 as Carbon Paste Electrode Composite (2018) Analytical and Bioanalytical Electrochemistry, 10, pp. 1538-1547; Wibowo, D., Sufandy, Y., Irwan, I., Azis, T., Maulidiyah, M., Nurdin, M., Investigation of Nickel Slag Waste as a Modifier on Graphene-TiO2 Microstructure for Sensing Phenolic Compound (2020) Journal of Materials Science: Materials in Electronics, pp. 1-9; Sharma, V., Vashistha, V.K., Das, D.K., Biological and Electrochemical Studies of Macrocyclic Complexes of Iron and Cobalt (2021) Biointerface Research in Applied Chemistry, 11, pp. 7393-7399. , https://doi.org/10.33263/BRIAC111.73937399; Maulidiyah, M., Mardhan, F.T., Muzuni, Ansharullah, Natsir, M., Wibowo, D., Nurdin, M., Lignin Black Liquor Degradation on Oil Palm Empty Fruit Bunches Using Ilmenite (FeO.TiO2) and Its Activity as Antibacterial (2019) Proceedings of the Journal of Physics: Conference Series, 1242; Nicoara, A.I., Ene, V.L., Voicu, B.B., Bucur, M.A., Neacsu, I.A., Vasile, B.S., Iordache, F., Biocompatible Ag/Fe-Enhanced TiO2 Nanoparticles as an Effective Compound in Sunscreens (2020) Nanomaterials, 10, p. 570; Gherasim, O., Puiu, R.A., Bîrca, A.C., Burduşel, A.C., Grumezescu, A.M., (2020) An Updated Review on Silver Nanoparticles in Biomedicine, 10. , ISBN 4021318100; Arkusz, K., Nycz, M., Paradowska, E., Pijanowska, D.G., Electrochemical Stability of TiO2 Nanotubes Deposited with Silver and Gold Nanoparticles in Aqueous Environment (2021) Environmental Nanotechnology, Monitoring & Management, 15, p. 100401; Maulidiyah, Ritonga, H., Salamba, R., Wibowo, D., Nurdin, M., Organic Compound Rhodamine B Degradation by TiO2/Ti Electrode in a New Portable Reactor (2015) International Journal of ChemTech Research, 8, pp. 645-653; Muzakkar, M.Z., Azis, T., Rajiani, M.S.P., Maulidiyah, M., Irwan, I., Mustapa, F., Salim, L.O.A., Nurdin, M., The Effect of Calcogenate Sulfur on the Performance of the S-TiO2/Ti Electrode as a Photoelectrocatalytic Sensor for Phenolic Compounds (2021) Journal of Physics: Conference Series, 1763, p. 12069; Maulidiyah, Nurdin, M., Wibowo, D., Sani, A., Nano Tube Titanium Dioxide/ Titanium Electrode Fabrication with Nitrogen and Silver Metal Doped Anodizing Method: Performance Test of Organic Compound Rhodamine B Degradation (2015) Pharmacy and Pharmaceutical Sciences, 7, pp. 141-146; Wu, Z., Zhao, J., Yin, Z., Wang, X., Li, Z., Wang, X., Sensors and Actuators B: Chemical Highly Sensitive Photoelectrochemical Detection of Glucose Based on BiOBr/TiO2 Nanotube Array p-n Heterojunction Nanocomposites (2020) Sensors & Actuators: B. Chemical, 312, p. 127978. , https://doi.org/10.1016/j.snb.2020.127978; Gupta, K., Chundawat, T.S., Malek, N.A.N.N., Antibacterial, Antifungal, Photocatalytic Activities and Seed Germination Effect of Mycosynthesized Silver Nanoparticles Using Fusarium Oxysporum (2021) Biointerface Research in Applied Chemistry, 11, pp. 12082-12091. , https://doi.org/10.33263/BRIAC114.1208212091

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